Model
A monochromatic plane wave travels along +z through thin, ideal, lossless (except for the polarizer's absorbed component) elements at normal incidence.
Fully polarized light is a Jones vector J = (Ex, Ey); each element is a 2×2 matrix and a chain acts as
Jout = MN ⋯ M2 M1 Jin (element 1 met first, so its matrix is on the right).
Partially polarized light is the Stokes vector S = (S₀, S₁, S₂, S₃) with S₀ ≥ √(S₁² + S₂² + S₃²); each element is a real 4×4 Mueller matrix, Sout = 𝕄N ⋯ 𝕄1 Sin.
An element with axis at θ is R(−θ) M₀ R(θ).
- ψ, δ
- amplitude angle (tan ψ = |Ey|/|Ex|) and phase difference φy − φx of the input's polarized part
- p
- degree of polarization √(S₁² + S₂² + S₃²)/S₀, 0 ≤ p ≤ 1
- θ
- transmission axis (polarizer) or fast axis (retarder), from +x toward +y
- Γ
- retardance: extra phase of the slow-axis component, Jones matrix diag(1, eiΓ) in the element frame
- Δn, d, λ
- birefringence ne − no, plate thickness, vacuum wavelength; Γ = 2π|Δn| d/λ
- ρ
- rotation angle of a rotator (optical activity or Faraday rotation), positive from x toward y
- D
- depolarization of an ideal depolarizer, 𝕄 = diag(1, 1 − D, 1 − D, 1 − D)
- θe, χ
- ellipse orientation ½ atan2(S₂, S₁) and ellipticity angle ½ asin(S₃/√(S₁²+S₂²+S₃²)); axis ratio |tan χ|
Assumptions and validity: monochromatic light (so the retardance is a single number), ideal elements with no reflection loss or finite extinction ratio,
normal incidence, uniaxial A-plates with constant indices (no dispersion), and incoherent summation only through the Stokes description.
Crystal indices are near-589 nm values: quartz 1.5443/1.5534, MgF₂ 1.3777/1.3895, sapphire 1.7681/1.7599, calcite 1.6584/1.4864 (no/ne).
Derivation: from Jones matrices to Mueller matrices and the Poincaré sphere
Define the coherency matrix C = ⟨J J†⟩. For fully polarized light C has rank 1; incoherent mixtures add their C matrices, which is how unpolarized light (C = ½ I₀ 𝟙) is represented.
With σ₀ = 𝟙, σ₁ = diag(1, −1), σ₂ = [[0, 1], [1, 0]], σ₃ = [[0, −i], [i, 0]] the Stokes parameters are Si = tr(C σi), and C = ½ Σ Si σi.
A Jones element maps C → M C M†. Substituting C gives S′i = Σj 𝕄ij Sj with 𝕄ij = ½ tr(σi M σj M†).
The tool computes element Mueller matrices from closed forms and checks this identity in its tests.
For a retarder with fast axis along x, M = diag(1, eiΓ) multiplies Ex*Ey by eiΓ, so (S₂ + iS₃) → eiΓ(S₂ + iS₃) while S₀ and S₁ are unchanged:
a rotation of the sphere by Γ about the S₁ axis. Rotating the element by θ rotates (S₁, S₂) by 2θ, so the rotation axis becomes (cos 2θ, sin 2θ, 0).
Rotations preserve the length √(S₁² + S₂² + S₃²), hence the degree of polarization. A polarizer at θ gives S₀′ = ½(S₀ + S₁ cos 2θ + S₂ sin 2θ); for unpolarized light that is S₀/2 for every θ.
In a uniaxial A-plate the two eigen-polarizations are E ∥ c (extraordinary, index ne) and E ⊥ c (ordinary, no). After thickness d they have phases 2π n d/λ,
so their difference is δ(d) = 2π(nslow − nfast) d/λ. In a positive crystal (ne > no, quartz) the o-wave is fast and the fast axis is ⊥ c; in a negative crystal (calcite) the fast axis is ∥ c.
Worked example: designing a quarter-wave plate from quartz at 633 nm
Problem. A He-Ne laser (λ = 633 nm) is horizontally polarized. Make it circular with a crystalline-quartz A-plate (no = 1.5443, ne = 1.5534).
Find the zero-order thickness, the orientation of the optic axis, the handedness, and the retardance error if the same plate is used at 532 nm.
Solution. Δn = ne − no = +0.0091 (positive uniaxial), so the o-wave (E ⊥ c) is fast. Quarter-wave needs Δn d/λ = ¼:
d = λ/(4Δn) = 633 nm/(4 × 0.0091) ≈ 17.39 µm. The fast axis must be at ±45° to the input; with c at +45° the fast axis is at 135° ≡ −45°, which rotates H about the −45° point to S₃ = +1 (right-handed here).
At 532 nm, Γ/2π = 0.0091 × 17.39/0.532 ≈ 0.297 waves (107° instead of 90°); S₃ = sin 107° ≈ 0.956 and the axis ratio is tan(½ asin 0.956) ≈ 0.74 — noticeably elliptical.
A third-order plate (d ≈ 17.39 + 3 × 69.56 = 226.1 µm) is circular at 633 nm but its retardance error at 532 nm is (3.25)(633/532 − 1) ≈ 0.62 waves: multi-order plates are far more wavelength-sensitive.
Load “Quartz QWP (crystal)” and move λ to check each number.